Magnesium Chloride

MineralModerate dose evidence

Also known as: MgCl2, magnesium chloride hexahydrate, Mg chloride, magnesium chloride flakes

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A highly soluble magnesium salt sold as the hexahydrate, which is about 12% elemental magnesium. It is used in liquid magnesium drops, electrolyte powders, and some tablets, and is the form in several of the clinical trials from Mexican research groups. Solubility gives it good bioavailability relative to oxide, and its salty, bitter taste is the main formulation hurdle. It is also the raw material for topical magnesium products.

Research summary

Supplies fully ionized magnesium in solution for enzymatic, neuromuscular, and electrolyte functions; chloride contributes to fluid balance.

Dosage

Daily amounts, elemental (12% of the compound is the element).

Lowest studiedTypical rangeHighest studiedUpper limit
100 mg100–300 mg350 mg350 mg

NIH ODS — UL of 350 mg applies to supplemental magnesium only, not magnesium from food

Doses are elemental magnesium. Magnesium chloride hexahydrate (MgCl2·6H2O, MW 203.3) is ≈ 12% Mg; anhydrous MgCl2 is ≈ 25.5% but is hygroscopic and rarely used. Take with water or food; loose stools can occur at higher doses. Capped at the 350 mg supplemental UL.

Source material: brine or seawater evaporation; synthetic grades also available

As supplied: Hexahydrate ≈ 12% Mg; anhydrous ≈ 25% Mg

Forms of Magnesium

FormTypical doseElement %FormatsPrice
Magnesium Chloride100–300 mg12%Capsule, Powder, Tablet, Liquidlow
Magnesium Glycinate200–350 mg14%Capsule, Powder, Tabletlow
Magnesium Citrate150–350 mg16%Capsule, Powder, Tablet, Gummy, Liquidlow
Magnesium Oxide200–350 mg60%Capsule, Powder, Tablet, Gummylow
Magnesium L-Threonate100–144 mg7%Capsule, Powder, Tablethigh
Magnesium Malate100–350 mg16%Capsule, Powder, Tabletlow
Magnesium Taurate100–300 mg9%Capsule, Powder, Tabletmid

Format suitability

  • Capsule
  • Powder
  • Tablet
  • Softgel
  • Gummy
  • Liquid

Strongly bitter and salty; liquids and powders need flavor masking. Hygroscopic and deliquescent, so bulk powder must be kept dry and capsules may need desiccant. 200 mg elemental ≈ 1,670 mg of hexahydrate.

Formulation notes

Adds chloride to electrolyte formulas. Separate from bisphosphonates and some antibiotics.

  • Has an upper limit

Sources

  1. Magnesium — Health Professional Fact SheetNIH ODS
  2. Bioavailability of US commercial magnesium preparations (Firoz 2001)PubMed

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